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5 Industrial Plastics and Their Uses

These materials make up the base of 99% of plastics used in most industries.
by Lori Ditoro

Everywhere you look, you likely see many types of industrial plastic. Plastic is a light-weight, durable, inexpensive, and easily modified material. This is part of the reason its usage has increased rapidly and is still growing.

All plastic is industrialized, and different plastic products have distinct properties. These properties can be seen primarily in their:

  • Thermal-resistance
  • Physical and mechanical properties
  • Density
  • Structure

Plastic consists of polymers, which are large organic molecules. The molecules are composed of repeating carbon-based units or chains. Polymers are produced when molecules called monomers form long chains in a process called polymerization.

High-Performance Plastics for Critical Applications

This article focuses on engineered, high-performance plastics often used for or with critical sealing technology. Five base materials are used 99% of the time. They are often used to design compounds by adding fillers to suit specific applications, such as the following:

  • A throttle in an air seal
  • A lantern ring for a stuffing box
  • Bushings or bearings for shaft stabilization

The plastics used are important. These components cannot be constructed from any plastic on the shelf. These five are the primary bases for most industrial, high-performance plastics. Each has unique characteristics, strengths, and limitations. A plastic should be selected carefully to match the parameters of each application.

1. Polytetrafluoroethylene

Polytetrafluoroethylene (PTFE), a universal material, performs well in many applications. It is the most commoditized of the engineered industrial plastics because of its dependable nature for many purposes.

PTFE Example
An example of PTFE

PTFE has a wide temperature range and broad chemical resistance. An inexpensive option, it is compatible with most other materials . Table 1 details the material’s strengths and limitations.

StrengthsLimitations
Broad chemical resistanceCreep and cold flow
NonflammableRelatively soft
Flexible at low temperaturesLow thermal dissipation
Low coefficient of friction (COF)Poor dimensional stability
Stable at high temperaturesHigh material shrinkage
Relatively easy to processLow rigidity
HF resistanceLow electrical conductivity
Table 1. PTFE strengths and limitations

2. Polyethylene Terephthalate

Polyethylene terephthalate (PET)  is a very hard, dense material. It is primarily used for bearings and bushings. With a relatively low service temperature, it is only good to about 210℉.

PET plastic example
An example of PET

PET is primarily used in conjunction with proprietary fillers for vertical pump bushings. It is very dimensionally stable, fairly inexpensive, and easy to machine. Table 2 details its strengths and limitations.

StrengthsLimitations
Very rigid and strongLow melting point
Good dimensional stabilityNarrow chemical resistance
Low COF
Hydrophobic
Easy to machine
FDA approved for food and liquid contact
Table 2. PET strengths and limitations

3. Polyphenylene Sulfide

Polyphenylene Sulfide (PPS) is a higher cost, very hard material. It has a broad temperature range and chemical resistance. Sometimes, it is referred to as PET’s older, more established brother. PPS has about the same hardness as PET but with broader chemical and temperature resistance. Its range is 500℉ to 550℉.

PPS primarily appears as shaft stabilizing bushings. Anytime a shaft has run out or wobble, a PPS bushing stabilizes the shaft. It works in conjunction with the whole system:

  • The PPS bushing
  • A lantern ring
  • The packing

These all make up a stuffing box.

PPS Example
An example of PPS

Two types of PPS are available: linear and branched. Table 3 details the characteristics of each, and Table 4 lists the strengths and limitations of both.

LinearBranched
Long linear molecular chains similar to PTFEHigh rigidity
Higher tensile strength and elongationIncreased hardness
Better melt stabilityIncreased dimensional stability
Less prone to absorbing moistureIncreased creep resistance
Better impact resistanceMore difficult to process and generally requires pre-curing/cross-linking
Table 3. Linear and branched PPS characteristics
StrengthsLimitations
Excellent chemical and radiation resistanceCan be very brittle
Excellent water absorptionPoor resistance to chlorinated hydrocarbons (Example: vinyl chloride and chloromethane)
Dimensionally stableHigh cost
Superior abrasion resistanceChallenging to process
Continuous use up to 450℉
Table 4. PPS strengths and limitations

4. Polybenzimidazole

Polybenzimidazole (PBI) is a high-temperature material. it withstands temperatures up to almost 900℉. This makes it an ideal plastic when dealing with difficult, high-temperature chemical applications. It is chemically resistant and dimensionally stable. Many experts consider it the Lamborghini of materials because it can do almost anything.

StrengthsLimitations
Highest compressive strength of any unfilled resinCan be brittle
Excellent tensile and flexural strengthExpensive
Dimensionally stable
Very low creep
Low COF
Continuous use up to more than 800℉
Table 5. PBI strengths and limitations

5. Polyether Ether Ketone

Polyether ether ketone (PEEK) is most similar to PPS with the main difference that PEEK is not brittle. It is basically a flexible version of PPS with the same temperature range. The concern with PPS is that it might break or fracture. With PEEK that is not a concern. Therefore, this makes it the plastic of choice in many applications.

PEEK example
An example of PEEK

However, PEEK is more expensive partly because of this flexibility. It is often chosen for high-pressure applications. For example, PEEK might be used to make a lantern ring for a high-temperature and high-pressure application.

StrengthsLimitations
Excellent tensile strength, elongation, and wear propertiesNot suitable for nitric or sulfuric acid
Superior chemical resistanceExpensive
Withstands long exposure to high pressure water and steamDifficult to process
Excellent chemical resistance
Very low flammability
Resistant to Gamma radiation
Continuous use up to 500℉
Table 6. PEEK strengths and limitations

High-Performance Industrial Plastic Trends

The mass production of industrial plastics began in the 1950s, and since then, the industry has grown exponentially. Why? According to the Plastics Industry Association, it is the diversity of plastic applications that makes the industry so unique and able to continually expand. It has grown to include new materials and new markets that the industry’s earliest practitioners may never have expected or predicted.

Plastic technology continues to increase in terms of what plastics can do. They replace metal components in industrial applications because they are versatile, lighter and stronger. They also do not corrode. For example, lantern rings were once almost always made out of brass. Today, they are most likely made from PTFE or PEEK. Similarly, some materials that were once bronze are plastic now.

While these trends in the sealing industry occur, uses for plastics are expanding. Plastics are taking center stage in the automotive industry, particularly PBI, PPS, and PEEK. These plastics are noncorrosive and lighter than automotive components previously made of metal.

Another area of expansion is 3D printing plastic components for many different applications. Previously, machining an industrial plastic part for a specific purpose was impossible. Now, 3D printing may make it possible.

Once a plastic component is installed, it may have a very long life. The technology continues to improve, and over time, plastics will be seen in even more applications. Plastics are the future of many industrial applications. High-performance industrial plastics for the sealing industry will grow. They may also be used in previously unheard-of ways.

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About the Author
Lori Ditoro joined SEPCO in November 2018 as content marketing manager. Before that, she was content marketing strategist for Fluke Accelix; editorial director of the Process Flow Network, publishers of Water Technology, Processing, and Flow Control; editor of Pumps & Systems; and editor of Upstream Pumping. In her roles, Ditoro has learned about the process and manufacturing industries and the equipment and technology that keep plants and other facilities operating. She also developed a passion for telling the operators' and technicians' stories. She may be reached at lorid@sepco.com.

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